Acid-Base Properties of Salts
This page introduces the fundamental concepts of salt dissociation in water and its effect on pH. It explains how to predict the acidity or basicity of salt solutions based on their constituent ions.
Definition: Salts are ionic compounds formed from the neutralization reaction between an acid and a base.
The dissociation equations of acids are presented, showing how strong and weak acids behave differently in solution. For example:
Example: HCl → H+ + Cl- (strong acid, dissociates completely)
Example: HCN → H+ + CN- (weak acid, dissociates partially)
The page emphasizes that the strength of conjugate acids and bases is inversely related to their parent compounds.
Highlight: Anions that are conjugates of weak acids tend to be basic, while cations that are conjugates of weak bases tend to be acidic.
Vocabulary: Conjugate base - the species formed when an acid loses a proton.
The acidity, basicity, or neutrality of various ions is discussed:
- NO₂⁻ is basic (conjugate of a weak acid)
- Na+ is neutral (Group I metal ion)
- NH₄+ is acidic (conjugate of a weak base)
- ClO₄⁻ is neutral (conjugate of a strong acid)
Quote: "Some conjugate bases are strong & act like a base, doesn't do a good job @ accepting H+"
This information is crucial for understanding the pH of salt solutions and predicting whether a salt is acid or base or neutral.