Detecting Anions (Negative Ions)
Anions are the negative ions that balance out those positive cations, and each type has its own detective test that's surprisingly straightforward.
For carbonate ions, just add some acid to your solution. If you see bubbles of CO₂ fizzing up, you've found your carbonate! It's like adding vinegar to baking soda - same reaction principle.
Sulphate ions need barium chloride to reveal themselves. Add this reagent and watch for a white precipitate to confirm sulphates are lurking in your solution.
Halide ions (chloride, bromide, and iodide) require a two-step dance. First add nitric acid, then silver nitrate, and the colour of the precipitate tells the whole story. Chloride gives white, bromide creates cream, and iodide produces yellow.
Real Lab Results When scientists tested three mystery solutions, they found sodium carbonate orangeflame+carbonatebubbles, iron(III) sulphate orangeprecipitate+whitebariumreaction, and copper chloride greenflame+whitesilverreaction.