Polyatomic Ions & Molecular Compounds
Transition metals form ions by losing electrons from their outer s-orbitals first. This is why they can form multiple different ion charges - they have unfilled inner d-electron shells that can also lose electrons.
Ternary ionic compounds contain three or more elements, usually with one type of cation and one type of anion, where at least one is a polyatomic ion. For example, NH₄Cl (ammonium chloride) or Fe(OH)₃ (iron(III) hydroxide). When writing formulas with polyatomic ions, use parentheses and a subscript to show how many of those ions are present.
For binary molecular compounds (made of two nonmetals), we use a prefix system to show how many atoms of each element are present. The first element doesn't use "mono-" but the second does (for one atom). For example, NO is nitrogen monoxide, and Cl₂O₇ is dichlorine heptoxide.
Remember this! Ionic compounds form between metals and nonmetals, while molecular compounds form between nonmetals only. This distinction helps you know which naming system to use.
Acids are molecular compounds that release H⁺ when dissolved in water. Binary acids H+oneotherelement are named "hydro-elementic acid" like hydrochloric acid (HCl). Oxoacids follow a pattern based on their related polyatomic ions: "-ate" becomes "-ic acid" and "-ite" becomes "-ous acid."
Bases produce hydroxide ions (OH⁻) in water and are named by writing the cation first, followed by "hydroxide." Common examples include calcium hydroxide Ca(OH)₂ and ammonium hydroxide NH₄OH.