Electron Orbitals and Molecular Shapes
An orbital is a region with a high probability of finding an electron, with each orbital holding up to 2 electrons. Electrons fill orbitals in increasing energy order (1s, 2s, 2p, etc.), and they prefer to occupy orbitals singly before pairing up. Remember these key exceptions: 4s fills before 3d (but empties first when writing electron configurations), and elements like chromium (3d⁵4s¹) and copper (3d¹⁰4s¹) have unusual configurations so each electron can have its own orbital.
Molecular shapes depend on the arrangement of electron pairs around the central atom. Linear molecules likeCl−B−Cl have a 180° bond angle with two bonding pairs and no lone pairs. Tetrahedral molecules (like CH₄) have four bonding pairs arranged at 109.5° angles. Other important shapes include non-linear (like H₂O, 104.5°), trigonal planar (like BF₃, 120°), pyramidal (like NH₃, 107.5°), and octahedral (six bonding pairs at 90° angles).
A molecule's polarity depends on both bond polarity and molecular shape. Even with polar bonds, a molecule can be non-polar if its dipole moments cancel out. For example, CO₂ has polar C-O bonds, but the linear arrangement causes the dipoles to cancel, making the molecule non-polar. NH₃, however, has dipoles that don't cancel, making it polar.
Remember this! Lone pairs repel more strongly than bonding pairs, which is why water's H-O-H angle (104.5°) is smaller than the perfect tetrahedral angle (109.5°).