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Let's Learn About How Things Burn: Stoichiometry of Hydrocarbon Combustion

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Let's Learn About How Things Burn: Stoichiometry of Hydrocarbon Combustion
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Jay Gale

@jaygale_mnxt

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The document covers the fundamentals of stoichiometry of hydrocarbon combustion, focusing on chemical reactions, concentrations, and combustion of hydrocarbons. Key topics include:

  • Basics of moles, atomic mass, and chemical reactions
  • Stoichiometry of hydrocarbon oxidation
  • Types of oxidizers and fuel mixtures
  • Combustion of methane in air
  • Air-fuel ratios and equivalence ratios

2/17/2023

242

STOICHIOMETRY OF
COMBUSTION FUNDAMENTALS: moles and
kilomoles
Atomic unit mass:
1/12 12°C
1.66 10-27 kg
Atoms and molecules mass is defined

View

Air/Fuel Ratio (AFR) and Fuel/Air Ratio (FAR)

This page discusses two important ratios used in combustion analysis, particularly in aviation:

  1. Air/Fuel Ratio (AFR) = Air mass-flow / Fuel mass-flow
  2. Fuel/Air Ratio (FAR) = Fuel mass-flow / Air mass-flow

Vocabulary:

  • AFR (Air/Fuel Ratio): The ratio of air mass-flow to fuel mass-flow
  • FAR (Fuel/Air Ratio): The ratio of fuel mass-flow to air mass-flow

These ratios are essential for analyzing and optimizing combustion processes in various applications, especially in aircraft engines.

STOICHIOMETRY OF
COMBUSTION FUNDAMENTALS: moles and
kilomoles
Atomic unit mass:
1/12 12°C
1.66 10-27 kg
Atoms and molecules mass is defined

View

Chemical Reactions and Stoichiometry

This section delves into the principles of chemical reactions and stoichiometry. It uses a simple example to illustrate how species react in exact proportions.

Example: In the reaction A + 2B → C, 1 mole of A reacts with 2 moles of B to produce 1 mole of C.

Definition: Stoichiometry in chemical reactions refers to the exact proportions in which species react.

The page emphasizes the importance of understanding these proportions in chemical reactions, which is crucial for chemical reaction stoichiometry basics.

STOICHIOMETRY OF
COMBUSTION FUNDAMENTALS: moles and
kilomoles
Atomic unit mass:
1/12 12°C
1.66 10-27 kg
Atoms and molecules mass is defined

View

Example: Stoichiometric Air for Methane Burning

The final page begins an example calculation for determining the stoichiometric air required for methane (CH₄) combustion. This practical application demonstrates how to apply the principles of stoichiometry of hydrocarbon combustion to a real-world problem.

STOICHIOMETRY OF
COMBUSTION FUNDAMENTALS: moles and
kilomoles
Atomic unit mass:
1/12 12°C
1.66 10-27 kg
Atoms and molecules mass is defined

View

Burning of Lean Methane Mixture in Air

This section examines the combustion of a lean methane mixture in air, assuming a 5% air excess. The balanced equation for this reaction is:

CH₄ + 2.1O₂ + 7.9N₂ → CO₂ + 2H₂O + 7.9N₂ + 0.1O₂

Highlight: In a lean mixture combustion, there is excess oxygen present in the flue gas.

This example illustrates how the presence of excess air affects the combustion reaction and the resulting flue gas composition.

STOICHIOMETRY OF
COMBUSTION FUNDAMENTALS: moles and
kilomoles
Atomic unit mass:
1/12 12°C
1.66 10-27 kg
Atoms and molecules mass is defined

View

Flue Gas Composition for Stoichiometric Methane Combustion

This page analyzes the composition of flue gas resulting from the stoichiometric combustion of methane in air. It calculates the concentrations of CO₂, H₂O, and N₂ in the flue gas based on the number of moles of each component.

Example: In the flue gas, the concentrations are:

  • 9.5% CO₂
  • 19% H₂O
  • 71.5% N₂

These calculations demonstrate how to determine the composition of combustion products using stoichiometric principles.

STOICHIOMETRY OF
COMBUSTION FUNDAMENTALS: moles and
kilomoles
Atomic unit mass:
1/12 12°C
1.66 10-27 kg
Atoms and molecules mass is defined

View

Types of Oxidizers

This page discusses the various types of oxidizers used in combustion processes. The four main types of oxidizers covered are:

  1. Oxygen (O₂)
  2. Air (21% O₂ + 79% N₂)
  3. Air enriched with oxygen (O₂ > 21%)
  4. Compounds containing oxygen, such as nitrogen oxides (e.g., N₂O)

Understanding the different types of oxidizers is crucial for analyzing and optimizing combustion processes in various applications.

STOICHIOMETRY OF
COMBUSTION FUNDAMENTALS: moles and
kilomoles
Atomic unit mass:
1/12 12°C
1.66 10-27 kg
Atoms and molecules mass is defined

View

Stoichiometric Air

This section introduces the concept of stoichiometric air, which is the theoretical minimum amount of air required for complete combustion of a fuel.

Definition: Stoichiometric air is the minimum air required in a stoichiometric mixture, as determined by the equation of stoichiometry for the oxygen/fuel reaction.

The page explains that the actual combustion air depends on the assumed air excess, which is expressed using the equivalence ratio or stoichiometric ratio.

STOICHIOMETRY OF
COMBUSTION FUNDAMENTALS: moles and
kilomoles
Atomic unit mass:
1/12 12°C
1.66 10-27 kg
Atoms and molecules mass is defined

View

Fundamentals of Stoichiometry and Chemical Reactions

This page introduces the basic concepts of stoichiometry and chemical reactions. It covers the definitions of atomic unit mass, moles, and kilomoles, which are fundamental to understanding chemical reaction stoichiometry basics.

Definition: A mole is defined as 6.022 x 10^23 atoms, which is known as Avogadro's number.

Highlight: The volume of 1 mole of a perfect gas at 0°C and 1 atm pressure is 22.4141 liters.

The page also explains that the mass of one mole (or kilomole) is equal to the relative atomic mass in grams (or kilograms).

STOICHIOMETRY OF
COMBUSTION FUNDAMENTALS: moles and
kilomoles
Atomic unit mass:
1/12 12°C
1.66 10-27 kg
Atoms and molecules mass is defined

View

Types of Combustible Mixtures

This page categorizes fuel mixtures into three types based on their composition relative to the stoichiometric ratio:

  1. Rich mixture: Excess of fuel
  2. Stoichiometric mixture: Exact stoichiometric content of fuel and oxygen
  3. Lean mixture: Excess of oxidizer

Understanding these mixture types is crucial for optimizing combustion processes and controlling emissions in various applications.

STOICHIOMETRY OF
COMBUSTION FUNDAMENTALS: moles and
kilomoles
Atomic unit mass:
1/12 12°C
1.66 10-27 kg
Atoms and molecules mass is defined

View

Species Concentrations and Fractions

This page discusses how to express the amounts of different species in a mixture. It introduces three important concepts:

  1. Concentration of a species
  2. Mole fraction
  3. Mass fraction

Vocabulary:

  • Concentration: The amount of a species per unit volume
  • Mole fraction: The number of moles of a species divided by the total number of moles of all species
  • Mass fraction: The mass of a species divided by the total mass of all species

These concepts are essential for understanding and calculating the composition of mixtures in stoichiometry of hydrocarbon combustion.

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Let's Learn About How Things Burn: Stoichiometry of Hydrocarbon Combustion

user profile picture

Jay Gale

@jaygale_mnxt

·

1 Follower

Follow

The document covers the fundamentals of stoichiometry of hydrocarbon combustion, focusing on chemical reactions, concentrations, and combustion of hydrocarbons. Key topics include:

  • Basics of moles, atomic mass, and chemical reactions
  • Stoichiometry of hydrocarbon oxidation
  • Types of oxidizers and fuel mixtures
  • Combustion of methane in air
  • Air-fuel ratios and equivalence ratios

2/17/2023

242

 

Chemistry

10

STOICHIOMETRY OF
COMBUSTION FUNDAMENTALS: moles and
kilomoles
Atomic unit mass:
1/12 12°C
1.66 10-27 kg
Atoms and molecules mass is defined

Sign up to see the content. It's free!

Access to all documents

Improve your grades

Join milions of students

By signing up you accept Terms of Service and Privacy Policy

Air/Fuel Ratio (AFR) and Fuel/Air Ratio (FAR)

This page discusses two important ratios used in combustion analysis, particularly in aviation:

  1. Air/Fuel Ratio (AFR) = Air mass-flow / Fuel mass-flow
  2. Fuel/Air Ratio (FAR) = Fuel mass-flow / Air mass-flow

Vocabulary:

  • AFR (Air/Fuel Ratio): The ratio of air mass-flow to fuel mass-flow
  • FAR (Fuel/Air Ratio): The ratio of fuel mass-flow to air mass-flow

These ratios are essential for analyzing and optimizing combustion processes in various applications, especially in aircraft engines.

STOICHIOMETRY OF
COMBUSTION FUNDAMENTALS: moles and
kilomoles
Atomic unit mass:
1/12 12°C
1.66 10-27 kg
Atoms and molecules mass is defined

Sign up to see the content. It's free!

Access to all documents

Improve your grades

Join milions of students

By signing up you accept Terms of Service and Privacy Policy

Chemical Reactions and Stoichiometry

This section delves into the principles of chemical reactions and stoichiometry. It uses a simple example to illustrate how species react in exact proportions.

Example: In the reaction A + 2B → C, 1 mole of A reacts with 2 moles of B to produce 1 mole of C.

Definition: Stoichiometry in chemical reactions refers to the exact proportions in which species react.

The page emphasizes the importance of understanding these proportions in chemical reactions, which is crucial for chemical reaction stoichiometry basics.

STOICHIOMETRY OF
COMBUSTION FUNDAMENTALS: moles and
kilomoles
Atomic unit mass:
1/12 12°C
1.66 10-27 kg
Atoms and molecules mass is defined

Sign up to see the content. It's free!

Access to all documents

Improve your grades

Join milions of students

By signing up you accept Terms of Service and Privacy Policy

Example: Stoichiometric Air for Methane Burning

The final page begins an example calculation for determining the stoichiometric air required for methane (CH₄) combustion. This practical application demonstrates how to apply the principles of stoichiometry of hydrocarbon combustion to a real-world problem.

STOICHIOMETRY OF
COMBUSTION FUNDAMENTALS: moles and
kilomoles
Atomic unit mass:
1/12 12°C
1.66 10-27 kg
Atoms and molecules mass is defined

Sign up to see the content. It's free!

Access to all documents

Improve your grades

Join milions of students

By signing up you accept Terms of Service and Privacy Policy

Burning of Lean Methane Mixture in Air

This section examines the combustion of a lean methane mixture in air, assuming a 5% air excess. The balanced equation for this reaction is:

CH₄ + 2.1O₂ + 7.9N₂ → CO₂ + 2H₂O + 7.9N₂ + 0.1O₂

Highlight: In a lean mixture combustion, there is excess oxygen present in the flue gas.

This example illustrates how the presence of excess air affects the combustion reaction and the resulting flue gas composition.

STOICHIOMETRY OF
COMBUSTION FUNDAMENTALS: moles and
kilomoles
Atomic unit mass:
1/12 12°C
1.66 10-27 kg
Atoms and molecules mass is defined

Sign up to see the content. It's free!

Access to all documents

Improve your grades

Join milions of students

By signing up you accept Terms of Service and Privacy Policy

Flue Gas Composition for Stoichiometric Methane Combustion

This page analyzes the composition of flue gas resulting from the stoichiometric combustion of methane in air. It calculates the concentrations of CO₂, H₂O, and N₂ in the flue gas based on the number of moles of each component.

Example: In the flue gas, the concentrations are:

  • 9.5% CO₂
  • 19% H₂O
  • 71.5% N₂

These calculations demonstrate how to determine the composition of combustion products using stoichiometric principles.

STOICHIOMETRY OF
COMBUSTION FUNDAMENTALS: moles and
kilomoles
Atomic unit mass:
1/12 12°C
1.66 10-27 kg
Atoms and molecules mass is defined

Sign up to see the content. It's free!

Access to all documents

Improve your grades

Join milions of students

By signing up you accept Terms of Service and Privacy Policy

Types of Oxidizers

This page discusses the various types of oxidizers used in combustion processes. The four main types of oxidizers covered are:

  1. Oxygen (O₂)
  2. Air (21% O₂ + 79% N₂)
  3. Air enriched with oxygen (O₂ > 21%)
  4. Compounds containing oxygen, such as nitrogen oxides (e.g., N₂O)

Understanding the different types of oxidizers is crucial for analyzing and optimizing combustion processes in various applications.

STOICHIOMETRY OF
COMBUSTION FUNDAMENTALS: moles and
kilomoles
Atomic unit mass:
1/12 12°C
1.66 10-27 kg
Atoms and molecules mass is defined

Sign up to see the content. It's free!

Access to all documents

Improve your grades

Join milions of students

By signing up you accept Terms of Service and Privacy Policy

Stoichiometric Air

This section introduces the concept of stoichiometric air, which is the theoretical minimum amount of air required for complete combustion of a fuel.

Definition: Stoichiometric air is the minimum air required in a stoichiometric mixture, as determined by the equation of stoichiometry for the oxygen/fuel reaction.

The page explains that the actual combustion air depends on the assumed air excess, which is expressed using the equivalence ratio or stoichiometric ratio.

STOICHIOMETRY OF
COMBUSTION FUNDAMENTALS: moles and
kilomoles
Atomic unit mass:
1/12 12°C
1.66 10-27 kg
Atoms and molecules mass is defined

Sign up to see the content. It's free!

Access to all documents

Improve your grades

Join milions of students

By signing up you accept Terms of Service and Privacy Policy

Fundamentals of Stoichiometry and Chemical Reactions

This page introduces the basic concepts of stoichiometry and chemical reactions. It covers the definitions of atomic unit mass, moles, and kilomoles, which are fundamental to understanding chemical reaction stoichiometry basics.

Definition: A mole is defined as 6.022 x 10^23 atoms, which is known as Avogadro's number.

Highlight: The volume of 1 mole of a perfect gas at 0°C and 1 atm pressure is 22.4141 liters.

The page also explains that the mass of one mole (or kilomole) is equal to the relative atomic mass in grams (or kilograms).

STOICHIOMETRY OF
COMBUSTION FUNDAMENTALS: moles and
kilomoles
Atomic unit mass:
1/12 12°C
1.66 10-27 kg
Atoms and molecules mass is defined

Sign up to see the content. It's free!

Access to all documents

Improve your grades

Join milions of students

By signing up you accept Terms of Service and Privacy Policy

Types of Combustible Mixtures

This page categorizes fuel mixtures into three types based on their composition relative to the stoichiometric ratio:

  1. Rich mixture: Excess of fuel
  2. Stoichiometric mixture: Exact stoichiometric content of fuel and oxygen
  3. Lean mixture: Excess of oxidizer

Understanding these mixture types is crucial for optimizing combustion processes and controlling emissions in various applications.

STOICHIOMETRY OF
COMBUSTION FUNDAMENTALS: moles and
kilomoles
Atomic unit mass:
1/12 12°C
1.66 10-27 kg
Atoms and molecules mass is defined

Sign up to see the content. It's free!

Access to all documents

Improve your grades

Join milions of students

By signing up you accept Terms of Service and Privacy Policy

Species Concentrations and Fractions

This page discusses how to express the amounts of different species in a mixture. It introduces three important concepts:

  1. Concentration of a species
  2. Mole fraction
  3. Mass fraction

Vocabulary:

  • Concentration: The amount of a species per unit volume
  • Mole fraction: The number of moles of a species divided by the total number of moles of all species
  • Mass fraction: The mass of a species divided by the total mass of all species

These concepts are essential for understanding and calculating the composition of mixtures in stoichiometry of hydrocarbon combustion.

Can't find what you're looking for? Explore other subjects.

Knowunity is the # 1 ranked education app in five European countries

Knowunity was a featured story by Apple and has consistently topped the app store charts within the education category in Germany, Italy, Poland, Switzerland and United Kingdom. Join Knowunity today and help millions of students around the world.

Ranked #1 Education App

Download in

Google Play

Download in

App Store

Knowunity is the # 1 ranked education app in five European countries

4.9+

Average App Rating

13 M

Students use Knowunity

#1

In Education App Charts in 12 Countries

950 K+

Students uploaded study notes

Still not sure? Look at what your fellow peers are saying...

iOS User

I love this app so much [...] I recommend Knowunity to everyone!!! I went from a C to an A with it :D

Stefan S, iOS User

The application is very simple and well designed. So far I have found what I was looking for :D

SuSSan, iOS User

Love this App ❤️, I use it basically all the time whenever I'm studying