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Dec 7, 2025

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Understanding Enthalpy Changes in Thermochemistry

Energy changes in chemical reactions are absolutely crucial for understanding... Show more

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9.1-Types of Enthalpy change

Key Lacts:
senergy
cannot be created
or destroyed
Enthalpy (H)=
the measure of
Cheat energy
present in a
chemi

Types of Enthalpy Change

Ever wondered why some reactions make things hot whilst others make them cold? It's all about enthalpy - the measure of heat energy present in any chemical system. Energy can never be created or destroyed, only transferred between the reaction system and its surroundings.

Enthalpy change (ΔH) tells you exactly how much energy gets released or absorbed during a chemical reaction. When reactions release energy to the surroundings, they're exothermic and have a negative ΔH value - you'll notice the temperature goes up.

When reactions absorb energy from the surroundings, they're endothermic with a positive ΔH value, causing temperatures to drop. The units are always measured in kJ mol⁻¹.

Quick Tip: Remember that exothermic reactions feel warm because they're giving out energy, whilst endothermic reactions feel cool because they're taking energy in from their surroundings.

9.1-Types of Enthalpy change

Key Lacts:
senergy
cannot be created
or destroyed
Enthalpy (H)=
the measure of
Cheat energy
present in a
chemi

Exothermic Enthalpy Profile Diagrams

Picture this: methane burning in oxygen CH4+2O2CO2+2H2OCH₄ + 2O₂ → CO₂ + 2H₂O - a classic exothermic reaction you see every time someone lights a gas cooker. The activation energy (Ea) represents the minimum energy bump that reactants need to overcome before the reaction kicks off.

In exothermic reactions, energy is needed initially to break existing bonds in the reactants. However, when new bonds form in the products, they release much more energy than was originally put in.

The enthalpy profile diagram shows reactants starting high and products ending up at a lower energy level. The difference between these levels is your negative ΔH value - that's the excess energy that gets released as heat.

Remember: Think of exothermic reactions like rolling a ball down a hill - once you give it that initial push (activation energy), it releases loads of energy as it rolls down to a lower level.

9.1-Types of Enthalpy change

Key Lacts:
senergy
cannot be created
or destroyed
Enthalpy (H)=
the measure of
Cheat energy
present in a
chemi

Endothermic Enthalpy Profile Diagrams

Now consider calcium carbonate breaking down when heated CaCO3CO2+CaOCaCO₃ → CO₂ + CaO - this is endothermic because you need to keep pumping in energy for it to happen. The activation energy barrier still exists, but here's the key difference from exothermic reactions.

In endothermic processes, breaking the original bonds requires more energy than you get back when forming the new bonds. This means the products end up at a higher energy level than the reactants started at.

The enthalpy profile shows this upward energy change clearly - reactants begin low and products finish high. The positive ΔH value represents all that extra energy that had to be absorbed from the surroundings to make the reaction work.

Memory Aid: Endothermic reactions are like pushing a boulder uphill - you're constantly putting energy in, and the final position has more stored energy than where you started.

9.1-Types of Enthalpy change

Key Lacts:
senergy
cannot be created
or destroyed
Enthalpy (H)=
the measure of
Cheat energy
present in a
chemi

Standard Conditions

Here's something that trips up loads of students: enthalpy changes vary depending on conditions. That's why chemists use standard conditions to ensure everyone's comparing like with like when they quote ΔH values.

Standard conditions are defined as 100 kPa pressure, 298 K temperature (that's 25°C), and 1 mol dm⁻³ for any solutions involved. When enthalpy changes are measured under these conditions, they get the special symbol ΔH⊖.

The standard state refers to the physical state each substance would naturally be in under standard conditions. For example, water's standard state is liquid, whilst oxygen exists as a gas.

Exam Tip: Always remember to convert Celsius to Kelvin by adding 273 - this conversion appears in loads of exam questions and it's easy marks if you get it right!



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The app is very easy to use and well designed. I have found everything I was looking for so far and have been able to learn a lot from the presentations! I will definitely use the app for a class assignment! And of course it also helps a lot as an inspiration.

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iOS user

This app is really great. There are so many study notes and help [...]. My problem subject is French, for example, and the app has so many options for help. Thanks to this app, I have improved my French. I would recommend it to anyone.

Samantha Klich

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Wow, I am really amazed. I just tried the app because I've seen it advertised many times and was absolutely stunned. This app is THE HELP you want for school and above all, it offers so many things, such as workouts and fact sheets, which have been VERY helpful to me personally.

Anna

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I think it’s very much worth it and you’ll end up using it a lot once you get the hang of it and even after looking at others notes you can still ask your Artificial intelligence buddy the question and ask to simplify it if you still don’t get it!!! In the end I think it’s worth it 😊👍 ⚠️Also DID I MENTION ITS FREEE YOU DON’T HAVE TO PAY FOR ANYTHING AND STILL GET YOUR GRADES IN PERFECTLY❗️❗️⚠️

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Knowunity is the BEST app I’ve used in a minute. This is not an ai review or anything this is genuinely coming from a 7th grade student (I know 2011 im young) but dude this app is a 10/10 i have maintained a 3.8 gpa and have plenty of time for gaming. I love it and my mom is just happy I got good grades

Brad T

Android user

Not only did it help me find the answer but it also showed me alternative ways to solve it. I was horrible in math and science but now I have an a in both subjects. Thanks for the help🤍🤍

David K

iOS user

The app's just great! All I have to do is enter the topic in the search bar and I get the response real fast. I don't have to watch 10 YouTube videos to understand something, so I'm saving my time. Highly recommended!

Sudenaz Ocak

Android user

In school I was really bad at maths but thanks to the app, I am doing better now. I am so grateful that you made the app.

Greenlight Bonnie

Android user

I found this app a couple years ago and it has only gotten better since then. I really love it because it can help with written questions and photo questions. Also, it can find study guides that other people have made as well as flashcard sets and practice tests. The free version is also amazing for students who might not be able to afford it. Would 100% recommend

Aubrey

iOS user

Best app if you're in Highschool or Junior high. I have been using this app for 2 school years and it's the best, it's good if you don't have anyone to help you with school work.😋🩷🎀

Marco B

iOS user

THE QUIZES AND FLASHCARDS ARE SO USEFUL AND I LOVE THE SCHOOLGPT. IT ALSO IS LITREALLY LIKE CHATGPT BUT SMARTER!! HELPED ME WITH MY MASCARA PROBLEMS TOO!! AS WELL AS MY REAL SUBJECTS ! DUHHH 😍😁😲🤑💗✨🎀😮

Elisha

iOS user

This app is phenomenal down to the correct info and the various topics you can study! I greatly recommend it for people who struggle with procrastination and those who need homework help. It has been perfectly accurate for world 1 history as far as I’ve seen! Geometry too!

Paul T

iOS user

The app is very easy to use and well designed. I have found everything I was looking for so far and have been able to learn a lot from the presentations! I will definitely use the app for a class assignment! And of course it also helps a lot as an inspiration.

Stefan S

iOS user

This app is really great. There are so many study notes and help [...]. My problem subject is French, for example, and the app has so many options for help. Thanks to this app, I have improved my French. I would recommend it to anyone.

Samantha Klich

Android user

Wow, I am really amazed. I just tried the app because I've seen it advertised many times and was absolutely stunned. This app is THE HELP you want for school and above all, it offers so many things, such as workouts and fact sheets, which have been VERY helpful to me personally.

Anna

iOS user

I think it’s very much worth it and you’ll end up using it a lot once you get the hang of it and even after looking at others notes you can still ask your Artificial intelligence buddy the question and ask to simplify it if you still don’t get it!!! In the end I think it’s worth it 😊👍 ⚠️Also DID I MENTION ITS FREEE YOU DON’T HAVE TO PAY FOR ANYTHING AND STILL GET YOUR GRADES IN PERFECTLY❗️❗️⚠️

Thomas R

iOS user

Knowunity is the BEST app I’ve used in a minute. This is not an ai review or anything this is genuinely coming from a 7th grade student (I know 2011 im young) but dude this app is a 10/10 i have maintained a 3.8 gpa and have plenty of time for gaming. I love it and my mom is just happy I got good grades

Brad T

Android user

Not only did it help me find the answer but it also showed me alternative ways to solve it. I was horrible in math and science but now I have an a in both subjects. Thanks for the help🤍🤍

David K

iOS user

The app's just great! All I have to do is enter the topic in the search bar and I get the response real fast. I don't have to watch 10 YouTube videos to understand something, so I'm saving my time. Highly recommended!

Sudenaz Ocak

Android user

In school I was really bad at maths but thanks to the app, I am doing better now. I am so grateful that you made the app.

Greenlight Bonnie

Android user

I found this app a couple years ago and it has only gotten better since then. I really love it because it can help with written questions and photo questions. Also, it can find study guides that other people have made as well as flashcard sets and practice tests. The free version is also amazing for students who might not be able to afford it. Would 100% recommend

Aubrey

iOS user

Best app if you're in Highschool or Junior high. I have been using this app for 2 school years and it's the best, it's good if you don't have anyone to help you with school work.😋🩷🎀

Marco B

iOS user

THE QUIZES AND FLASHCARDS ARE SO USEFUL AND I LOVE THE SCHOOLGPT. IT ALSO IS LITREALLY LIKE CHATGPT BUT SMARTER!! HELPED ME WITH MY MASCARA PROBLEMS TOO!! AS WELL AS MY REAL SUBJECTS ! DUHHH 😍😁😲🤑💗✨🎀😮

Elisha

iOS user

This app is phenomenal down to the correct info and the various topics you can study! I greatly recommend it for people who struggle with procrastination and those who need homework help. It has been perfectly accurate for world 1 history as far as I’ve seen! Geometry too!

Paul T

iOS user

 

Chemistry

163

Dec 7, 2025

4 pages

Understanding Enthalpy Changes in Thermochemistry

Energy changes in chemical reactions are absolutely crucial for understanding chemistry. This topic covers enthalpy - the heat energy involved when bonds break and form during reactions - and why some reactions release heat whilst others absorb it.

9.1-Types of Enthalpy change

Key Lacts:
senergy
cannot be created
or destroyed
Enthalpy (H)=
the measure of
Cheat energy
present in a
chemi

Sign up to see the contentIt's free!

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Join milions of students

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Types of Enthalpy Change

Ever wondered why some reactions make things hot whilst others make them cold? It's all about enthalpy - the measure of heat energy present in any chemical system. Energy can never be created or destroyed, only transferred between the reaction system and its surroundings.

Enthalpy change (ΔH) tells you exactly how much energy gets released or absorbed during a chemical reaction. When reactions release energy to the surroundings, they're exothermic and have a negative ΔH value - you'll notice the temperature goes up.

When reactions absorb energy from the surroundings, they're endothermic with a positive ΔH value, causing temperatures to drop. The units are always measured in kJ mol⁻¹.

Quick Tip: Remember that exothermic reactions feel warm because they're giving out energy, whilst endothermic reactions feel cool because they're taking energy in from their surroundings.

9.1-Types of Enthalpy change

Key Lacts:
senergy
cannot be created
or destroyed
Enthalpy (H)=
the measure of
Cheat energy
present in a
chemi

Sign up to see the contentIt's free!

Access to all documents

Improve your grades

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By signing up you accept Terms of Service and Privacy Policy

Exothermic Enthalpy Profile Diagrams

Picture this: methane burning in oxygen CH4+2O2CO2+2H2OCH₄ + 2O₂ → CO₂ + 2H₂O - a classic exothermic reaction you see every time someone lights a gas cooker. The activation energy (Ea) represents the minimum energy bump that reactants need to overcome before the reaction kicks off.

In exothermic reactions, energy is needed initially to break existing bonds in the reactants. However, when new bonds form in the products, they release much more energy than was originally put in.

The enthalpy profile diagram shows reactants starting high and products ending up at a lower energy level. The difference between these levels is your negative ΔH value - that's the excess energy that gets released as heat.

Remember: Think of exothermic reactions like rolling a ball down a hill - once you give it that initial push (activation energy), it releases loads of energy as it rolls down to a lower level.

9.1-Types of Enthalpy change

Key Lacts:
senergy
cannot be created
or destroyed
Enthalpy (H)=
the measure of
Cheat energy
present in a
chemi

Sign up to see the contentIt's free!

Access to all documents

Improve your grades

Join milions of students

By signing up you accept Terms of Service and Privacy Policy

Endothermic Enthalpy Profile Diagrams

Now consider calcium carbonate breaking down when heated CaCO3CO2+CaOCaCO₃ → CO₂ + CaO - this is endothermic because you need to keep pumping in energy for it to happen. The activation energy barrier still exists, but here's the key difference from exothermic reactions.

In endothermic processes, breaking the original bonds requires more energy than you get back when forming the new bonds. This means the products end up at a higher energy level than the reactants started at.

The enthalpy profile shows this upward energy change clearly - reactants begin low and products finish high. The positive ΔH value represents all that extra energy that had to be absorbed from the surroundings to make the reaction work.

Memory Aid: Endothermic reactions are like pushing a boulder uphill - you're constantly putting energy in, and the final position has more stored energy than where you started.

9.1-Types of Enthalpy change

Key Lacts:
senergy
cannot be created
or destroyed
Enthalpy (H)=
the measure of
Cheat energy
present in a
chemi

Sign up to see the contentIt's free!

Access to all documents

Improve your grades

Join milions of students

By signing up you accept Terms of Service and Privacy Policy

Standard Conditions

Here's something that trips up loads of students: enthalpy changes vary depending on conditions. That's why chemists use standard conditions to ensure everyone's comparing like with like when they quote ΔH values.

Standard conditions are defined as 100 kPa pressure, 298 K temperature (that's 25°C), and 1 mol dm⁻³ for any solutions involved. When enthalpy changes are measured under these conditions, they get the special symbol ΔH⊖.

The standard state refers to the physical state each substance would naturally be in under standard conditions. For example, water's standard state is liquid, whilst oxygen exists as a gas.

Exam Tip: Always remember to convert Celsius to Kelvin by adding 273 - this conversion appears in loads of exam questions and it's easy marks if you get it right!

We thought you’d never ask...

What is the Knowunity AI companion?

Our AI companion is specifically built for the needs of students. Based on the millions of content pieces we have on the platform we can provide truly meaningful and relevant answers to students. But its not only about answers, the companion is even more about guiding students through their daily learning challenges, with personalised study plans, quizzes or content pieces in the chat and 100% personalisation based on the students skills and developments.

Where can I download the Knowunity app?

You can download the app in the Google Play Store and in the Apple App Store.

Is Knowunity really free of charge?

That's right! Enjoy free access to study content, connect with fellow students, and get instant help – all at your fingertips.

Most popular content: Enthalpy Change (δh)

Most popular content in Chemistry

Most popular content

Can't find what you're looking for? Explore other subjects.

Students love us — and so will you.

4.9/5

App Store

4.8/5

Google Play

The app is very easy to use and well designed. I have found everything I was looking for so far and have been able to learn a lot from the presentations! I will definitely use the app for a class assignment! And of course it also helps a lot as an inspiration.

Stefan S

iOS user

This app is really great. There are so many study notes and help [...]. My problem subject is French, for example, and the app has so many options for help. Thanks to this app, I have improved my French. I would recommend it to anyone.

Samantha Klich

Android user

Wow, I am really amazed. I just tried the app because I've seen it advertised many times and was absolutely stunned. This app is THE HELP you want for school and above all, it offers so many things, such as workouts and fact sheets, which have been VERY helpful to me personally.

Anna

iOS user

I think it’s very much worth it and you’ll end up using it a lot once you get the hang of it and even after looking at others notes you can still ask your Artificial intelligence buddy the question and ask to simplify it if you still don’t get it!!! In the end I think it’s worth it 😊👍 ⚠️Also DID I MENTION ITS FREEE YOU DON’T HAVE TO PAY FOR ANYTHING AND STILL GET YOUR GRADES IN PERFECTLY❗️❗️⚠️

Thomas R

iOS user

Knowunity is the BEST app I’ve used in a minute. This is not an ai review or anything this is genuinely coming from a 7th grade student (I know 2011 im young) but dude this app is a 10/10 i have maintained a 3.8 gpa and have plenty of time for gaming. I love it and my mom is just happy I got good grades

Brad T

Android user

Not only did it help me find the answer but it also showed me alternative ways to solve it. I was horrible in math and science but now I have an a in both subjects. Thanks for the help🤍🤍

David K

iOS user

The app's just great! All I have to do is enter the topic in the search bar and I get the response real fast. I don't have to watch 10 YouTube videos to understand something, so I'm saving my time. Highly recommended!

Sudenaz Ocak

Android user

In school I was really bad at maths but thanks to the app, I am doing better now. I am so grateful that you made the app.

Greenlight Bonnie

Android user

I found this app a couple years ago and it has only gotten better since then. I really love it because it can help with written questions and photo questions. Also, it can find study guides that other people have made as well as flashcard sets and practice tests. The free version is also amazing for students who might not be able to afford it. Would 100% recommend

Aubrey

iOS user

Best app if you're in Highschool or Junior high. I have been using this app for 2 school years and it's the best, it's good if you don't have anyone to help you with school work.😋🩷🎀

Marco B

iOS user

THE QUIZES AND FLASHCARDS ARE SO USEFUL AND I LOVE THE SCHOOLGPT. IT ALSO IS LITREALLY LIKE CHATGPT BUT SMARTER!! HELPED ME WITH MY MASCARA PROBLEMS TOO!! AS WELL AS MY REAL SUBJECTS ! DUHHH 😍😁😲🤑💗✨🎀😮

Elisha

iOS user

This app is phenomenal down to the correct info and the various topics you can study! I greatly recommend it for people who struggle with procrastination and those who need homework help. It has been perfectly accurate for world 1 history as far as I’ve seen! Geometry too!

Paul T

iOS user

The app is very easy to use and well designed. I have found everything I was looking for so far and have been able to learn a lot from the presentations! I will definitely use the app for a class assignment! And of course it also helps a lot as an inspiration.

Stefan S

iOS user

This app is really great. There are so many study notes and help [...]. My problem subject is French, for example, and the app has so many options for help. Thanks to this app, I have improved my French. I would recommend it to anyone.

Samantha Klich

Android user

Wow, I am really amazed. I just tried the app because I've seen it advertised many times and was absolutely stunned. This app is THE HELP you want for school and above all, it offers so many things, such as workouts and fact sheets, which have been VERY helpful to me personally.

Anna

iOS user

I think it’s very much worth it and you’ll end up using it a lot once you get the hang of it and even after looking at others notes you can still ask your Artificial intelligence buddy the question and ask to simplify it if you still don’t get it!!! In the end I think it’s worth it 😊👍 ⚠️Also DID I MENTION ITS FREEE YOU DON’T HAVE TO PAY FOR ANYTHING AND STILL GET YOUR GRADES IN PERFECTLY❗️❗️⚠️

Thomas R

iOS user

Knowunity is the BEST app I’ve used in a minute. This is not an ai review or anything this is genuinely coming from a 7th grade student (I know 2011 im young) but dude this app is a 10/10 i have maintained a 3.8 gpa and have plenty of time for gaming. I love it and my mom is just happy I got good grades

Brad T

Android user

Not only did it help me find the answer but it also showed me alternative ways to solve it. I was horrible in math and science but now I have an a in both subjects. Thanks for the help🤍🤍

David K

iOS user

The app's just great! All I have to do is enter the topic in the search bar and I get the response real fast. I don't have to watch 10 YouTube videos to understand something, so I'm saving my time. Highly recommended!

Sudenaz Ocak

Android user

In school I was really bad at maths but thanks to the app, I am doing better now. I am so grateful that you made the app.

Greenlight Bonnie

Android user

I found this app a couple years ago and it has only gotten better since then. I really love it because it can help with written questions and photo questions. Also, it can find study guides that other people have made as well as flashcard sets and practice tests. The free version is also amazing for students who might not be able to afford it. Would 100% recommend

Aubrey

iOS user

Best app if you're in Highschool or Junior high. I have been using this app for 2 school years and it's the best, it's good if you don't have anyone to help you with school work.😋🩷🎀

Marco B

iOS user

THE QUIZES AND FLASHCARDS ARE SO USEFUL AND I LOVE THE SCHOOLGPT. IT ALSO IS LITREALLY LIKE CHATGPT BUT SMARTER!! HELPED ME WITH MY MASCARA PROBLEMS TOO!! AS WELL AS MY REAL SUBJECTS ! DUHHH 😍😁😲🤑💗✨🎀😮

Elisha

iOS user

This app is phenomenal down to the correct info and the various topics you can study! I greatly recommend it for people who struggle with procrastination and those who need homework help. It has been perfectly accurate for world 1 history as far as I’ve seen! Geometry too!

Paul T

iOS user