Calculating Entropy Changes
Now for the maths bit (don't worry, it's easier than it looks)! Every substance has a standard entropy value (S°) that's always positive, measured in JK⁻¹mol⁻¹.
The formula you need is: ΔS = ΣS°(products) - ΣS°(reactants). It's just products minus reactants, exactly like enthalpy calculations.
Let's try it with 2SO(g) + O₂(g) → 2NO₂(g). First, find the standard entropy values: SO = +212, O₂ = +205, NO₂ = +240. Then calculate: Products = 240 × 2 = 480, Reactants = 422 + 205 = 627.
So ΔS = 480 - 627 = -147 JK⁻¹mol⁻¹. The negative value makes sense because we're going from 3 gas molecules to 2.
Remember: Always multiply by the coefficients in the balanced equation, just like with any other calculation!