Calculating Reaction Rates
When measuring reaction rates, it's crucial to maintain a constant temperature throughout your experiment. Even small temperature changes can dramatically affect how fast a reaction proceeds.
For the cyclopropane example, we can calculate the average rate over the first 5 minutes:
Rate = Δpropene ÷ time = 0.27 ÷ 5 = 0.054 mol dm⁻³ min⁻¹
Notice on concentration-time graphs that curves typically become shallower over time, indicating the reaction is slowing down. The most accurate way to determine the rate at a specific moment is by drawing a tangent to the curve at that point.
Remember: The smaller your time intervals for measurement, the more accurate your reaction rate calculations will be. This is especially important for fast reactions!
By analyzing these rates, you can understand exactly how reaction speed changes throughout the process, which is key information for controlling chemical reactions.