Boiling Point Elevation
Adding a solute to a solvent raises its boiling point! Since solutes lower vapor pressure, the solution must be heated to a higher temperature to reach atmospheric pressure.
When the vapor pressure equals atmospheric pressure, boiling occurs. Because solutions have lower vapor pressure than pure solvents, they need more heat to reach this point.
For non-electrolytes, the equation ΔTₑ = Kₑ × m applies, where Kₑ is the boiling-point elevation constant 0.512°C/mforwater and m is molality. For electrolytes, we use ΔTₑ = i × Kₑ × m, where i represents the number of ions formed.
For example, a solution containing 20g of ethyl alcohol in 250g of water would boil at 100.89°C instead of 100°C.
Science Hack: When cooking pasta in saltwater, it cooks faster not just because the water boils at a higher temperature, but because the salt also changes the pasta's protein structure!