Atomic and Ionic Radii Trends
Ever wonder why atoms change size across the periodic table? Atomic radius (half the distance between identical atoms in a molecule) follows predictable patterns. As you move across a period, radii generally decrease because electrons are added to the same energy level while proton count increases, pulling electrons closer. Moving down a group, radii increase because electrons enter higher energy levels, farther from the nucleus.
When atoms become ions, size changes dramatically. Ionic radius measures the size of an ion. Metals tend to form positive cations (losing electrons and becoming smaller), while nonmetals form negative anions (gaining electrons and becoming larger). Going across a period, both cation and anion radii decrease, but there's a significant size jump when switching from cations to anions.
Transition metals don't follow the typical patterns. As you move across transition metals in a period, the d sublevel fills, causing atomic radii to decrease slightly before increasing. Cation sizes vary without a consistent trend.
💡 Think of it like this: Across a period, the nucleus pulls electrons harder (smaller atoms), while down a group, you're adding new "floors" to the electron "apartment building" (larger atoms).
Ionization energy reveals how tightly atoms hold their electrons. It's the energy needed to remove an electron from a gaseous atom or ion. First ionization energy generally increases across periods exceptbetweengroups2−13and15−16 and decreases down groups. This happens because electrons are closer to the nucleus across a period but farther away down a group.