Practical Example: Calculating Buffer pH
This section provides a practical example of how to calculate the pH of a buffer solution, which is a common type of question in A Level Chemistry buffer calculations.
Example: Ethanoic acid buffer
Given:
- 125 cm³ of 0.8 mol dm⁻³ ethanoic acid (CH3COOH)
- 75 cm³ of 1 mol dm⁻³ sodium ethanoate (CH3COONa)
- Ka of ethanoic acid = 1.74 × 10⁻⁵ mol dm⁻³
Step 1: Calculate new concentrations after mixing
CH3COOH = (0.8 × 125) / 200 = 0.5 mol dm⁻³
CH3COO− = (1 × 75) / 200 = 0.375 mol dm⁻³
Step 2: Use the equation H+ = Ka × HA / A−
H+ = (1.74 × 10⁻⁵ × 0.5) / 0.375 = 2.32 × 10⁻⁵ mol dm⁻³
Step 3: Calculate pH
pH = -log(2.32 × 10⁻⁵) = 4.63
Highlight: This example demonstrates how to prepare a buffer solution with a specific pH and how to calculate pH of buffer solution given molarity and volume.
Example: If you needed to prepare a pH 4 buffer solution, you would adjust the ratio of acid to conjugate base to achieve this pH.
Understanding these calculations is crucial for mastering buffers in A Level Chemistry OCR and other exam boards.