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Understanding Titration Curves: Strong Acid vs. Strong Base and How They Change pH

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Understanding Titration Curves: Strong Acid vs. Strong Base and How They Change pH
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Laila

@lailaaa__

·

27 Followers

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A titration curve of strong acid and strong base shows the gradual change in pH as one solution is added to another, helping us understand acid-base reactions.

The curve begins when a strong base like sodium hydroxide (NaOH) is slowly added to a strong acid like hydrochloric acid (HCl). At first, the pH stays very low around 1-3 as the acid is still in excess. As more base is added, the pH starts to rise gradually. When we reach the equivalence point - where the moles of acid exactly equal the moles of base - there's a dramatic jump in pH. This sharp vertical rise is characteristic of strong acid-strong base titrations, with the equivalence point occurring at pH 7.

When we investigate pH changes in acid-base titrations, we see different patterns depending on the strength of the acid and base used. The effect of weak acid strong base titration on pH produces a curve that's more gradual compared to strong acid-strong base titrations. With weak acids, we see a buffer region where the pH changes very slowly despite adding more base. This happens because weak acids only partially dissociate in water, creating a mixture of acid and its conjugate base that resists pH changes. The equivalence point also occurs at a pH above 7, typically around 8-10, because the salt formed from a weak acid and strong base undergoes hydrolysis. Understanding these differences helps chemists choose appropriate indicators and determine unknown concentrations accurately. The shape and features of titration curves provide valuable information about the strength of acids and bases, their concentrations, and the progress of neutralization reactions.

2/5/2023

143

pH
16
8
6
11
7
5
9
13
12
14
5
x
10
Strong base +
15
20
Weak acel
25
X
3
Base added /cm ³
30
35
40
Ov
W
Vi
a
e PH
12
10
8
6
4
4
Strons, asiel

View

Practical Investigation of pH Changes in Titrations

To investigate pH changes in acid-base titrations, precise measurements and careful experimental technique are essential. The process requires proper calibration of pH meters and systematic addition of titrant.

Highlight: Calibration using standard buffer solutions (pH 4.00, 7.00, and 9.20) ensures accurate pH measurements throughout the titration process.

The experimental setup typically includes:

  • Calibrated pH meter or probe
  • Burettes for precise volume measurements
  • Appropriate concentration of solutions (usually 0.1 M)
  • Stirring apparatus for thorough mixing

When conducting the titration, small volume increments (0.2-2.0 cm³) of base are added to the acid solution while monitoring pH changes. This allows for detailed plotting of the titration curve and accurate determination of the equivalence point.

Vocabulary: The equivalence point represents the exact moment when stoichiometrically equivalent amounts of acid and base have reacted.

pH
16
8
6
11
7
5
9
13
12
14
5
x
10
Strong base +
15
20
Weak acel
25
X
3
Base added /cm ³
30
35
40
Ov
W
Vi
a
e PH
12
10
8
6
4
4
Strons, asiel

View

Safety Considerations in Acid-Base Titrations

Laboratory safety is paramount when working with acids and bases. Proper protective equipment and careful handling procedures must be followed to prevent accidents and ensure accurate results.

Definition: Corrosive substances are materials that can cause severe damage to living tissue through chemical action.

Key safety measures include:

  • Wearing splash-proof goggles and appropriate protective clothing
  • Using fume hoods when working with concentrated solutions
  • Proper handling and disposal of glassware
  • Immediate washing with water if skin contact occurs

The risk assessment should consider specific hazards associated with each chemical used. For example, sodium hydroxide requires extra caution due to its highly corrosive nature, while weak acids like ethanoic acid present lower but still significant risks.

Highlight: Always have access to eyewash stations and safety showers when handling corrosive substances.

pH
16
8
6
11
7
5
9
13
12
14
5
x
10
Strong base +
15
20
Weak acel
25
X
3
Base added /cm ³
30
35
40
Ov
W
Vi
a
e PH
12
10
8
6
4
4
Strons, asiel

View

Data Analysis and Interpretation

Accurate data collection and interpretation are crucial for understanding titration behavior. Results should be recorded systematically and analyzed carefully to draw meaningful conclusions.

Example: In a typical weak acid-strong base titration, pH readings might progress as follows:

  • Initial pH: 3.80 (pure weak acid)
  • Buffer region: pH 4.54-5.82 (gradual increase)
  • Equivalence point: sharp increase to pH 8-9
  • Post-equivalence: gradual increase to pH >10

The data should be plotted carefully to create smooth titration curves. Multiple trials ensure reliability and allow for calculation of experimental error. Particular attention should be paid to the equivalence point region, where the most dramatic pH changes occur.

Highlight: The shape and position of the equivalence point provide valuable information about the strength of the acids and bases involved in the titration.

pH
16
8
6
11
7
5
9
13
12
14
5
x
10
Strong base +
15
20
Weak acel
25
X
3
Base added /cm ³
30
35
40
Ov
W
Vi
a
e PH
12
10
8
6
4
4
Strons, asiel

View

Understanding Acid-Base Titration Curves and pH Changes

A thorough understanding of titration curve of strong acid and strong base reactions is essential for mastering chemical analysis. When acids and bases react, they produce distinct pH patterns that can be visualized through titration curves.

Definition: A titration curve is a graphical representation showing how pH changes as one solution (titrant) is gradually added to another solution (analyte).

The shape of titration curves varies significantly depending on the strength of the acids and bases involved. For strong acid-strong base titrations, the curve shows a sharp vertical jump at the equivalence point, reaching pH 7. This occurs because the H+ from the acid and OH- from the base combine in exact proportions to form water.

When examining the effect of weak acid strong base titration on pH, the curve appears different. The pH changes more gradually initially due to the buffer region created by the weak acid and its conjugate base. At the equivalence point, the solution becomes basic (pH > 7) because the conjugate base of the weak acid undergoes hydrolysis.

Example: When titrating ethanoic acid (CH₃COOH) with sodium hydroxide (NaOH), the pH starts around 3-4 and gradually increases until reaching approximately pH 8-9 at the equivalence point.

pH
16
8
6
11
7
5
9
13
12
14
5
x
10
Strong base +
15
20
Weak acel
25
X
3
Base added /cm ³
30
35
40
Ov
W
Vi
a
e PH
12
10
8
6
4
4
Strons, asiel

View

Understanding pH Changes in Strong and Weak Acid-Base Titrations

When we investigate pH changes in acid-base titrations, the resulting data reveals important patterns about how acids and bases interact. The titration curve of strong acid and strong base shows distinctive characteristics that help us understand neutralization reactions. As base is added to an acidic solution, the pH changes follow a predictable pattern, starting from low values around 1-2 and eventually reaching basic pH levels above 12.

Definition: A titration curve plots pH against the volume of titrant added, showing how acidity changes during the neutralization process.

The data shows that during the initial stages of titration (0-18 mL of base added), pH changes are gradual. However, near the equivalence point (around 19-21 mL), there's a dramatic jump in pH values. This sharp increase indicates the point where the moles of acid and base are equal. After the equivalence point, additional base causes smaller increases in pH as the solution becomes increasingly basic.

The effect of weak acid strong base titration on pH produces a different curve shape compared to strong acid-strong base titrations. In weak acid titrations, we observe a more gradual pH change near the equivalence point due to the buffering effect of the weak acid and its conjugate base. The data shows pH values starting around 3-4 and rising more steadily throughout the titration process.

Highlight: The equivalence point in acid-base titrations is marked by a rapid change in pH, but this change is more dramatic for strong acid-strong base combinations compared to weak acid-strong base systems.

pH
16
8
6
11
7
5
9
13
12
14
5
x
10
Strong base +
15
20
Weak acel
25
X
3
Base added /cm ³
30
35
40
Ov
W
Vi
a
e PH
12
10
8
6
4
4
Strons, asiel

View

Analyzing Buffer Regions and Endpoint Detection in Titrations

Buffer regions play a crucial role in controlling pH changes during titrations. The data demonstrates how buffer solutions resist pH changes when small amounts of acid or base are added. This is particularly evident in the weak acid titration results, where pH changes are more gradual compared to strong acid systems.

Example: In the weak acid titration data, adding base between 14-18 mL shows smaller pH changes (around 0.2-0.3 units) compared to the same volume addition in strong acid titrations (changes of 1-2 pH units).

The endpoint detection becomes more challenging in weak acid-strong base titrations due to the less dramatic pH change. The data shows that while strong acid-strong base titrations have a clear vertical jump in pH at the endpoint, weak acid systems show a more gradual increase. This difference affects the choice of indicators and the precision of endpoint detection.

Multiple trials help ensure accuracy in pH measurements. The experimental data includes repeated measurements, showing variations between tests that typically fall within 0.2-0.3 pH units. This repetition helps establish reliable average values and identifies potential sources of experimental error.

Vocabulary: The equivalence point represents the theoretical point where stoichiometrically equivalent amounts of acid and base have been combined, while the endpoint is the experimentally observed color change of an indicator.

pH
16
8
6
11
7
5
9
13
12
14
5
x
10
Strong base +
15
20
Weak acel
25
X
3
Base added /cm ³
30
35
40
Ov
W
Vi
a
e PH
12
10
8
6
4
4
Strons, asiel

View

Introduction and Theory

This section outlines the fundamental concepts behind acid-base titrations and their pH changes. The practical focuses on investigating reactions between weak acids with strong bases and strong acids with weak bases.

Definition: A titration is a technique where a solution of known concentration (titrant) is added to a solution being studied (analyte) to determine its concentration.

Highlight: The equivalence point occurs when titrant and analyte are present in stoichiometric amounts, often indicated by a dramatic pH change.

Example: In a strong acid-strong base titration (like HCl and NaOH), the pH at equivalence point is exactly 7.

Vocabulary: Titration curve - A graphical representation showing pH changes during a titration process.

The introduction provides detailed explanations of three types of titrations:

  1. Weak base-strong acid titrations (resulting in acidic solutions)
  2. Strong base-weak acid titrations (resulting in alkaline solutions)
  3. Strong acid-strong base titrations (resulting in neutral solutions)
pH
16
8
6
11
7
5
9
13
12
14
5
x
10
Strong base +
15
20
Weak acel
25
X
3
Base added /cm ³
30
35
40
Ov
W
Vi
a
e PH
12
10
8
6
4
4
Strons, asiel

View

pH
16
8
6
11
7
5
9
13
12
14
5
x
10
Strong base +
15
20
Weak acel
25
X
3
Base added /cm ³
30
35
40
Ov
W
Vi
a
e PH
12
10
8
6
4
4
Strons, asiel

View

pH
16
8
6
11
7
5
9
13
12
14
5
x
10
Strong base +
15
20
Weak acel
25
X
3
Base added /cm ³
30
35
40
Ov
W
Vi
a
e PH
12
10
8
6
4
4
Strons, asiel

View

Can't find what you're looking for? Explore other subjects.

Knowunity is the # 1 ranked education app in five European countries

Knowunity was a featured story by Apple and has consistently topped the app store charts within the education category in Germany, Italy, Poland, Switzerland and United Kingdom. Join Knowunity today and help millions of students around the world.

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Download in

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Knowunity is the # 1 ranked education app in five European countries

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Students use Knowunity

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In Education App Charts in 12 Countries

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Love this App ❤️, I use it basically all the time whenever I'm studying

Understanding Titration Curves: Strong Acid vs. Strong Base and How They Change pH

user profile picture

Laila

@lailaaa__

·

27 Followers

Follow

A titration curve of strong acid and strong base shows the gradual change in pH as one solution is added to another, helping us understand acid-base reactions.

The curve begins when a strong base like sodium hydroxide (NaOH) is slowly added to a strong acid like hydrochloric acid (HCl). At first, the pH stays very low around 1-3 as the acid is still in excess. As more base is added, the pH starts to rise gradually. When we reach the equivalence point - where the moles of acid exactly equal the moles of base - there's a dramatic jump in pH. This sharp vertical rise is characteristic of strong acid-strong base titrations, with the equivalence point occurring at pH 7.

When we investigate pH changes in acid-base titrations, we see different patterns depending on the strength of the acid and base used. The effect of weak acid strong base titration on pH produces a curve that's more gradual compared to strong acid-strong base titrations. With weak acids, we see a buffer region where the pH changes very slowly despite adding more base. This happens because weak acids only partially dissociate in water, creating a mixture of acid and its conjugate base that resists pH changes. The equivalence point also occurs at a pH above 7, typically around 8-10, because the salt formed from a weak acid and strong base undergoes hydrolysis. Understanding these differences helps chemists choose appropriate indicators and determine unknown concentrations accurately. The shape and features of titration curves provide valuable information about the strength of acids and bases, their concentrations, and the progress of neutralization reactions.

2/5/2023

143

 

12/13

 

Chemistry

6

pH
16
8
6
11
7
5
9
13
12
14
5
x
10
Strong base +
15
20
Weak acel
25
X
3
Base added /cm ³
30
35
40
Ov
W
Vi
a
e PH
12
10
8
6
4
4
Strons, asiel

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Practical Investigation of pH Changes in Titrations

To investigate pH changes in acid-base titrations, precise measurements and careful experimental technique are essential. The process requires proper calibration of pH meters and systematic addition of titrant.

Highlight: Calibration using standard buffer solutions (pH 4.00, 7.00, and 9.20) ensures accurate pH measurements throughout the titration process.

The experimental setup typically includes:

  • Calibrated pH meter or probe
  • Burettes for precise volume measurements
  • Appropriate concentration of solutions (usually 0.1 M)
  • Stirring apparatus for thorough mixing

When conducting the titration, small volume increments (0.2-2.0 cm³) of base are added to the acid solution while monitoring pH changes. This allows for detailed plotting of the titration curve and accurate determination of the equivalence point.

Vocabulary: The equivalence point represents the exact moment when stoichiometrically equivalent amounts of acid and base have reacted.

pH
16
8
6
11
7
5
9
13
12
14
5
x
10
Strong base +
15
20
Weak acel
25
X
3
Base added /cm ³
30
35
40
Ov
W
Vi
a
e PH
12
10
8
6
4
4
Strons, asiel

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Access to all documents

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Join milions of students

By signing up you accept Terms of Service and Privacy Policy

Safety Considerations in Acid-Base Titrations

Laboratory safety is paramount when working with acids and bases. Proper protective equipment and careful handling procedures must be followed to prevent accidents and ensure accurate results.

Definition: Corrosive substances are materials that can cause severe damage to living tissue through chemical action.

Key safety measures include:

  • Wearing splash-proof goggles and appropriate protective clothing
  • Using fume hoods when working with concentrated solutions
  • Proper handling and disposal of glassware
  • Immediate washing with water if skin contact occurs

The risk assessment should consider specific hazards associated with each chemical used. For example, sodium hydroxide requires extra caution due to its highly corrosive nature, while weak acids like ethanoic acid present lower but still significant risks.

Highlight: Always have access to eyewash stations and safety showers when handling corrosive substances.

pH
16
8
6
11
7
5
9
13
12
14
5
x
10
Strong base +
15
20
Weak acel
25
X
3
Base added /cm ³
30
35
40
Ov
W
Vi
a
e PH
12
10
8
6
4
4
Strons, asiel

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Data Analysis and Interpretation

Accurate data collection and interpretation are crucial for understanding titration behavior. Results should be recorded systematically and analyzed carefully to draw meaningful conclusions.

Example: In a typical weak acid-strong base titration, pH readings might progress as follows:

  • Initial pH: 3.80 (pure weak acid)
  • Buffer region: pH 4.54-5.82 (gradual increase)
  • Equivalence point: sharp increase to pH 8-9
  • Post-equivalence: gradual increase to pH >10

The data should be plotted carefully to create smooth titration curves. Multiple trials ensure reliability and allow for calculation of experimental error. Particular attention should be paid to the equivalence point region, where the most dramatic pH changes occur.

Highlight: The shape and position of the equivalence point provide valuable information about the strength of the acids and bases involved in the titration.

pH
16
8
6
11
7
5
9
13
12
14
5
x
10
Strong base +
15
20
Weak acel
25
X
3
Base added /cm ³
30
35
40
Ov
W
Vi
a
e PH
12
10
8
6
4
4
Strons, asiel

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Access to all documents

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Join milions of students

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Understanding Acid-Base Titration Curves and pH Changes

A thorough understanding of titration curve of strong acid and strong base reactions is essential for mastering chemical analysis. When acids and bases react, they produce distinct pH patterns that can be visualized through titration curves.

Definition: A titration curve is a graphical representation showing how pH changes as one solution (titrant) is gradually added to another solution (analyte).

The shape of titration curves varies significantly depending on the strength of the acids and bases involved. For strong acid-strong base titrations, the curve shows a sharp vertical jump at the equivalence point, reaching pH 7. This occurs because the H+ from the acid and OH- from the base combine in exact proportions to form water.

When examining the effect of weak acid strong base titration on pH, the curve appears different. The pH changes more gradually initially due to the buffer region created by the weak acid and its conjugate base. At the equivalence point, the solution becomes basic (pH > 7) because the conjugate base of the weak acid undergoes hydrolysis.

Example: When titrating ethanoic acid (CH₃COOH) with sodium hydroxide (NaOH), the pH starts around 3-4 and gradually increases until reaching approximately pH 8-9 at the equivalence point.

pH
16
8
6
11
7
5
9
13
12
14
5
x
10
Strong base +
15
20
Weak acel
25
X
3
Base added /cm ³
30
35
40
Ov
W
Vi
a
e PH
12
10
8
6
4
4
Strons, asiel

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Understanding pH Changes in Strong and Weak Acid-Base Titrations

When we investigate pH changes in acid-base titrations, the resulting data reveals important patterns about how acids and bases interact. The titration curve of strong acid and strong base shows distinctive characteristics that help us understand neutralization reactions. As base is added to an acidic solution, the pH changes follow a predictable pattern, starting from low values around 1-2 and eventually reaching basic pH levels above 12.

Definition: A titration curve plots pH against the volume of titrant added, showing how acidity changes during the neutralization process.

The data shows that during the initial stages of titration (0-18 mL of base added), pH changes are gradual. However, near the equivalence point (around 19-21 mL), there's a dramatic jump in pH values. This sharp increase indicates the point where the moles of acid and base are equal. After the equivalence point, additional base causes smaller increases in pH as the solution becomes increasingly basic.

The effect of weak acid strong base titration on pH produces a different curve shape compared to strong acid-strong base titrations. In weak acid titrations, we observe a more gradual pH change near the equivalence point due to the buffering effect of the weak acid and its conjugate base. The data shows pH values starting around 3-4 and rising more steadily throughout the titration process.

Highlight: The equivalence point in acid-base titrations is marked by a rapid change in pH, but this change is more dramatic for strong acid-strong base combinations compared to weak acid-strong base systems.

pH
16
8
6
11
7
5
9
13
12
14
5
x
10
Strong base +
15
20
Weak acel
25
X
3
Base added /cm ³
30
35
40
Ov
W
Vi
a
e PH
12
10
8
6
4
4
Strons, asiel

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Analyzing Buffer Regions and Endpoint Detection in Titrations

Buffer regions play a crucial role in controlling pH changes during titrations. The data demonstrates how buffer solutions resist pH changes when small amounts of acid or base are added. This is particularly evident in the weak acid titration results, where pH changes are more gradual compared to strong acid systems.

Example: In the weak acid titration data, adding base between 14-18 mL shows smaller pH changes (around 0.2-0.3 units) compared to the same volume addition in strong acid titrations (changes of 1-2 pH units).

The endpoint detection becomes more challenging in weak acid-strong base titrations due to the less dramatic pH change. The data shows that while strong acid-strong base titrations have a clear vertical jump in pH at the endpoint, weak acid systems show a more gradual increase. This difference affects the choice of indicators and the precision of endpoint detection.

Multiple trials help ensure accuracy in pH measurements. The experimental data includes repeated measurements, showing variations between tests that typically fall within 0.2-0.3 pH units. This repetition helps establish reliable average values and identifies potential sources of experimental error.

Vocabulary: The equivalence point represents the theoretical point where stoichiometrically equivalent amounts of acid and base have been combined, while the endpoint is the experimentally observed color change of an indicator.

pH
16
8
6
11
7
5
9
13
12
14
5
x
10
Strong base +
15
20
Weak acel
25
X
3
Base added /cm ³
30
35
40
Ov
W
Vi
a
e PH
12
10
8
6
4
4
Strons, asiel

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Introduction and Theory

This section outlines the fundamental concepts behind acid-base titrations and their pH changes. The practical focuses on investigating reactions between weak acids with strong bases and strong acids with weak bases.

Definition: A titration is a technique where a solution of known concentration (titrant) is added to a solution being studied (analyte) to determine its concentration.

Highlight: The equivalence point occurs when titrant and analyte are present in stoichiometric amounts, often indicated by a dramatic pH change.

Example: In a strong acid-strong base titration (like HCl and NaOH), the pH at equivalence point is exactly 7.

Vocabulary: Titration curve - A graphical representation showing pH changes during a titration process.

The introduction provides detailed explanations of three types of titrations:

  1. Weak base-strong acid titrations (resulting in acidic solutions)
  2. Strong base-weak acid titrations (resulting in alkaline solutions)
  3. Strong acid-strong base titrations (resulting in neutral solutions)
pH
16
8
6
11
7
5
9
13
12
14
5
x
10
Strong base +
15
20
Weak acel
25
X
3
Base added /cm ³
30
35
40
Ov
W
Vi
a
e PH
12
10
8
6
4
4
Strons, asiel

Sign up to see the content. It's free!

Access to all documents

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pH
16
8
6
11
7
5
9
13
12
14
5
x
10
Strong base +
15
20
Weak acel
25
X
3
Base added /cm ³
30
35
40
Ov
W
Vi
a
e PH
12
10
8
6
4
4
Strons, asiel

Sign up to see the content. It's free!

Access to all documents

Improve your grades

Join milions of students

By signing up you accept Terms of Service and Privacy Policy

pH
16
8
6
11
7
5
9
13
12
14
5
x
10
Strong base +
15
20
Weak acel
25
X
3
Base added /cm ³
30
35
40
Ov
W
Vi
a
e PH
12
10
8
6
4
4
Strons, asiel

Sign up to see the content. It's free!

Access to all documents

Improve your grades

Join milions of students

By signing up you accept Terms of Service and Privacy Policy

Can't find what you're looking for? Explore other subjects.

Knowunity is the # 1 ranked education app in five European countries

Knowunity was a featured story by Apple and has consistently topped the app store charts within the education category in Germany, Italy, Poland, Switzerland and United Kingdom. Join Knowunity today and help millions of students around the world.

Ranked #1 Education App

Download in

Google Play

Download in

App Store

Knowunity is the # 1 ranked education app in five European countries

4.9+

Average App Rating

15 M

Students use Knowunity

#1

In Education App Charts in 12 Countries

950 K+

Students uploaded study notes

Still not sure? Look at what your fellow peers are saying...

iOS User

I love this app so much [...] I recommend Knowunity to everyone!!! I went from a C to an A with it :D

Stefan S, iOS User

The application is very simple and well designed. So far I have found what I was looking for :D

SuSSan, iOS User

Love this App ❤️, I use it basically all the time whenever I'm studying